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Zeta potential testing

Zeta potential analysis

The potential difference between the dispersion medium and the stationary layer of fluid attached to the particle is called Zeta potential and it is measured by a zeta potential analyzer. Zeta potential is the charge that develops at the interface between a solid surface and its liquid medium. A scientific term for electrokinetic potential in colloidal dispersions is Zeta potential. This potential, which is measured in MilliVolts, may arise by any of several mechanisms

The degree of electrostatic repulsion between adjacent, similarly charged particles in a dispersion is the magnitude of the Zeta potential. For small molecules and particles, a high zeta potential will confer stability, that is the solution or dispersion will resist aggregation. Attractive forces may exceed this repulsion and the dispersion may break and flocculate if the potential is small. Thus, colloids with high zeta potential (negative or positive) are electrically stabilized while colloids with low zeta potentials tend to coagulate or flocculate.

The zeta potential is connected to the nanoparticles' net surface load. It is important to determine the colloidal stability of charged particles and to consider your system's output under different conditions.

The measurement of zeta potential has important applications in a wide range of industries including; ceramics, pharmaceuticals, medicine, mineral processing, electronics, water purification and industrial waste treatment, Electrodeposition, Paper, Detergency. The nature and structure of the electric double layer at the particle-liquid interface are directly related to Zeta potential measurements. testing of zeta potential Its measurement gives detailed perception into the causes of dispersion, aggregation or flocculation, which can be applied to improve the formulation of dispersions, emulsions and suspensions.

Applications:
Biomedical
Characterizing the surface of organisms such as bacteria, blood cells, viruses etc is performed by Microelectrophoresis. Chemical methods of analysis can disrupt the organism, zeta potential measurement has the particular merit of providing information which refers precisely to the outermost regions of an organism. This is of particular value since the surface of these organisms is the sites of many phenomena of biological importance. The prime constituents of biological material (protein, lipid, polysaccharide, nucleic acid) exhibit characteristic charge behavior, the magnitude, sign and distribution of which deeply affects its interaction with any other surface or molecule. Changes in the zeta potential of blood elements, tissue cells, vessel walls or components of body fluids can produce metabolic changes or alterations in blood flow properties.
Clay technology
Plate-like particles present in clay, when come in contact with water, usually have negatively charged faces and positively charged edges. The physical properties of clay-water systems such as sedimentation, filtration, swelling, viscosity, yield stress and structural strength are extremely sensitive to the nature of the electric double layer around the particles and the tendency of the particles to aggregate. Wherever colloid stability and/or ion adsorption is involved, Zeta potential measurements provide appropriate information. Results for a concentrated suspension can be related to results of shear and consolidation tests. Control of the mechanical behavior of clay suspensions, using additives in the liquid phase, is also an important feature of soil treatment, oil well drilling, ceramics and other processes involving clay-like materials.
Soil Mechanics
To attain good aeration and drainage, it is required to maintain agricultural soil in the reasonably flocculated state and treatment with flocculants such as calcium salts or organic polyelectrolyte is a common practice. The movement of nutrients through soils is affected by the degree of flocculation of the soil. In road and building engineering, soils are sometimes stabilized against swelling by precipitating soaps onto the particles to reduce their hydrophilic nature and response to water. Conversely, canals are sometimes lined with clays which swell on contact with water to reduce seepage losses.
Oil Well Technology
In the drilling of oil wells a drilling mud is used as a coolant, for removing the cutting from the bore-hole and to seal the sides of the bore-hole with an impermeable filter cake. If the drilling mud is deflocculated then the pumping and sealing features of this operation are most effective. However, a certain amount of mud rigidity is required to prevent cuttings from falling to the bottom of the bore-hole during an interruption of circulation. These opposite requirements are reconciled by maintaining the drilling mud in a partially flocculated, thixotropic, state. If the drilling mud hardens, partial deflocculation can be effected by addition of a small amount of a polyphosphate which is a peptizing agent, the main function of this is to reverse the positive charge on the edge of the clay particles. The relatively small edge area of the clay particles makes this process economically attractive.
Ceramics
Mobility information is useful in the manufacture of felted ceramics which are produced by a paper making technique. Finely divided material and fibers are first made into an aqueous suspension. The charges on the surface of the fibers and particulate matter are measured and adjusted so that the particulate material is attracted and holds on the surface of the fiber. As the flocculated material settles, water is removed, and the flocked fibers form the felt, or compact.
Water purification and industrial waste
Generally municipal water supplies are obtained from sources that are contaminated with materials derived from soil, domestic sewage and industrial waste. Use of small quantities of flocculating agents eases the filtration of these contaminants. Electrophoretic measurements play an important part in the study of this flocculation process. Before being discharged into streams industrial and mining wastes are also treated by the addition of coagulating additives to accelerate settling of suspended matter. The optimum coagulation condition is obtained by using Zeta potential measurements for removal of particulate matter and organic dyestuffs from waste waters.
Electrodeposition for Corrosion Protection
The application of paint to metal objects such as automobile bodies, by electrodeposition is a major advance in corrosion protection. The metal object to be painted is made as the anode and the container as the cathode. The colloidal paint particles move through the aqueous electrolyte to the part being painted due to charge on the electric double layer. Electrophoretic mobility measurements are valuable in establishing the optimum pigment dispersion with various additives
Purification
In establishing optimum conditions for purification, Zeta potential measurements are useful in a number of chemical processes. For example, impurities in raw sugar cane juice may be removed by precipitating an inorganic material which serves to collect the impurities. The proper zeta potential is determined, and optimum conditions are maintained to reach maximum removal of these impurities through rapid sedimentation.
Measurement Mechanics at NISHKA Research
We conduct zeta potential measurements at NISHKA Research with a Malvern Zetasizer Nano ZS instrument fitted with a layer of 632 nm which is working at a detector angle of 173 degrees. A sample is placed into a single folded capillary cell in a zeta potential measurement. The cells have two-conductor electrodes, which contact the voltage applied on the external side of the instrument and fold it in, to contact the inside liquid sample.

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